Vera Popova
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Vera Yevstafievna Popova, née Vera Bogdanovskaya (Вера Евстафьевна Попова; 17 September 1867 – 8 May 1896) was a Russian
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe t ...
. She was one of the first female chemists in Russia, and the first Russian female author of a chemistry textbook. She "probably became the first woman to die in the cause of chemistry" as a result of an explosion in her laboratory.


Early life and education

Vera Bogdanovskaya was born in 1867 in Saint Petersburg. Her father, Evstafy Ivanovich Bogdanovsky, was a professor of surgery. Her parents arranged for their three children to be educated at home. In 1878, she began studying at the
Smolny Institute The Smolny Institute (russian: Смольный институт, ''Smol'niy institut'') is a Palladian edifice in Saint Petersburg that has played a major part in the history of Russia. History The building was commissioned from Giacomo Qua ...
at the age of 11. Starting in 1883 she spent four years at the
Bestuzhev Courses The Bestuzhev Courses (russian: Бестужевские курсы) in Saint Petersburg were the largest and most prominent women's higher education institution in Imperial Russia. The institute opened its doors in 1878. It was named after Kons ...
and after this she worked for two years in laboratories at the
Academy of Sciences An academy of sciences is a type of learned society or academy (as special scientific institution) dedicated to sciences that may or may not be state funded. Some state funded academies are tuned into national or royal (in case of the Unit ...
and the Military Surgical Academy. In 1889 Bogdanovskaya left Russia for Switzerland, where she undertook a doctorate in chemistry at the
University of Geneva The University of Geneva (French: ''Université de Genève'') is a public research university located in Geneva, Switzerland. It was founded in 1559 by John Calvin as a theological seminary. It remained focused on theology until the 17th centur ...
. She defended her research into
dibenzyl ketone Dibenzyl ketone, or 1,3-diphenylacetone, is an organic compound composed of two benzyl groups attached to a central carbonyl group. This results in the central carbonyl carbon atom being electrophilic and the two adjacent carbon atoms slightly nucl ...
in 1892. Bogdanovskaya wanted to work on H-C≡P (
methylidynephosphane Methylidynephosphane (phosphaethyne) is a chemical compound which was the first phosphaalkyne compound discovered, containing the unusual C≡P carbon-phosphorus triple bond. Description Methylidynephosphane is the phosphorus analogue of hydrog ...
), but had been persuaded to concentrate instead on dibenzyl ketone by her doctoral supervisor, Professor
Carl Gräbe Carl Gräbe (; 24 February 1841 – 19 January 1927) was a German industrial and academic chemist from Frankfurt am Main who held professorships in his field at Leipzig, Königsberg, and Geneva. He is known for the first synthesis of the ec ...
. She also worked with Dr Philippe Auguste Guye in Geneva, who was working on stereochemistry.


Career

Bogdanovskaya returned to Saint Petersburg in 1892 to work at the Bestuzhev Courses, where she taught chemistry. This was an institution founded in 1878 to encourage Russian women to stay in Russia to study. She was working as an assistant to Prof. L'vov teaching the first courses in stereochemistry. Her reputation as a lecturer and her knowledge of teaching enabled her to write her first book, a textbook on basic chemistry. She wrote reviews, translated academic papers on chemistry and, together with her professor, published the works of
Alexander Butlerov Alexander Mikhaylovich Butlerov (Алекса́ндр Миха́йлович Бу́тлеров; 15 September 1828 – 17 August 1886) was a Russian chemist, one of the principal creators of the theory of chemical structure (1857–1861 ...
, who had died in 1886.Anne C. Hughes, "Vera Evstaf'evna Bogdanovskaia," in
Marilyn Ogilvie Marilyn Bailey Ogilvie (born 1936) is an American historian of science known especially for her work on the history of women in science. She taught at Oklahoma Baptist University before becoming curator of the History of Science Collections and ...
,
Joy Harvey Joy Dorothy Harvey (born 1934) is an American historian of science. Life Harvey gained a PhD from Harvard University in 1983. She has been an associate editor of the Darwin Correspondence Project, and written a biography of Clémence Royer, Dar ...
, and Margaret Rossiter (eds.), ''Biographical Dictionary of Women in Science: Pioneering Lives from Ancient Times to the Mid-Twentieth Century.'' New York: Routledge, 2014; pg. 153.
Between 1891 and 1894, she published a number of papers based on her doctoral thesis. She was not just a chemist; she was also interested in entomology, writing and languages. In 1889, she published a description of work with bees. Bogdanovskaya published her own short stories, as well as her translations of the French short story writer
Guy de Maupassant Henri René Albert Guy de Maupassant (, ; ; 5 August 1850 – 6 July 1893) was a 19th-century French author, remembered as a master of the short story form, as well as a representative of the Naturalist school, who depicted human lives, destin ...
.


Personal life

Bogdanovskaya left Saint Petersburg and married General Jacob Kozmich Popov in 1895. He was older than she and a director of a military steel plant, and she demanded that he build her a laboratory where she could continue her chemistry. They lived in Izhevskii Zavod, a town under military control that was dedicated to weapon manufacture. It has been suggested that her marriage may have been one of convenience, as it was known that Russian women sometimes married just to escape the conventions of society.


Death

Popova died on 8 May 1896 (Gregorian calendar; 26 April in the Julian Calendar), (the date is sometimes given as 1897 in English sources) as a result of an explosion which occurred while she was attempting to synthesize H-C≡P (
methylidynephosphane Methylidynephosphane (phosphaethyne) is a chemical compound which was the first phosphaalkyne compound discovered, containing the unusual C≡P carbon-phosphorus triple bond. Description Methylidynephosphane is the phosphorus analogue of hydrog ...
), a chemical similar to hydrogen cyanide. She was 28.


Aftermath

H-C≡P, the chemical that she was trying to synthesize at the time of her death, was not successfully created until 1961 from phosphine and carbon. It is extremely
pyrophoric A substance is pyrophoric (from grc-gre, πυροφόρος, , 'fire-bearing') if it ignites spontaneously in air at or below (for gases) or within 5 minutes after coming into contact with air (for liquids and solids). Examples are organolit ...
and polymerizes easily at temperatures above −120 °C. Its triple point is −124 °C and it burns spontaneously even at low temperatures when exposed to air.


Legacy

Popova was given a substantial tribute in the ''Journal of the Russian Physical Chemical Society''. A shorter obituary appeared in the journal ''
Nature Nature, in the broadest sense, is the physical world or universe. "Nature" can refer to the phenomena of the physical world, and also to life in general. The study of nature is a large, if not the only, part of science. Although humans are ...
'' and a brief notice in the American journal ''
Science Science is a systematic endeavor that Scientific method, builds and organizes knowledge in the form of Testability, testable explanations and predictions about the universe. Science may be as old as the human species, and some of the earli ...
''. One report by the chemist
Vladimir Ipatieff Vladimir Nikolayevich Ipatieff (also Ipatyev; russian: Владимир Николаевич Ипатьев); (November 21, 1867 (November 9 OS) – November 29, 1952) was a Russian and American chemist. His most important contributions are in the ...
suggested that she may have been poisoned by her experiment or have committed suicide, but this view was not supported by other reports. Her early death led to a fund being created in her memory by her husband to assist female students. Her portrait was also displayed at the Women's College where she had trained. Popova is credited with classifying
dibenzyl ketone Dibenzyl ketone, or 1,3-diphenylacetone, is an organic compound composed of two benzyl groups attached to a central carbonyl group. This results in the central carbonyl carbon atom being electrophilic and the two adjacent carbon atoms slightly nucl ...
. This laid the foundation for synthetic acrylic resins created from
acetone cyanohydrin Acetone cyanohydrin (ACH) is an organic compound used in the production of methyl methacrylate, the monomer of the transparent plastic polymethyl methacrylate (PMMA), also known as acrylic. It liberates hydrogen cyanide easily, so it is used as a s ...
.


References

{{DEFAULTSORT:Popova, Vera 1867 births 1896 deaths 19th-century chemists Accidental deaths in Russia Explosions in Russia Chemists from the Russian Empire Educators from the Russian Empire 19th-century women scientists from the Russian Empire Deaths from laboratory accidents Explosions in 1896